Unimolecular Photodissociation Dynamics of Ketene (CH{sub 2}CO): The Singlet/Triplet Branching Ratio and Experimental Observation of the Vibrational L

by S K Kim

The rotational distributions of CO products from the dissociation of ketene at photolysis energies 10 cm{sup {minus}1} below, 56, 110, 200, 325, 425, 1,107, 1,435, 1,720, and 2,500 cm{sup {minus}1} above the singlet threshold, are measured in a supersonic free jet of ketene. The CO(v{double_prime} = 0) rotational distributions at 56, 110, 200, 325, and 425 cm{sup {minus}1} are bimodal. The peaks at low J s, which are due to CO from the singlet channel,...

• Format: Paperback
• Language: English
• ISBN: 1288542747
• ISBN13: 9781288542741
• Release Date: January 2013
• Publisher: Biblioscholar
• Length: 224 Pages
• Weight: 0.90 lbs.
• Dimensions: 0.5" x 7.4" x 9.7"