The Selective Physical Chemistry of Inorganic Chlorates and Perchlorates: A Chlorine Energetic Materials thesis

By Jared Ledgard

A complete guide to inorganic chlorates and perchlorates, including preparation, properties, and physical measurements. Topics include: Section 1: Introduction, A. Chlorine, An Element from the Gods'; B. Chlorine Isotopes; C; D. Sources of Chlorine, Chlorine Minerals, Section 2: Chlorine, Chloric acid and Perchloric acid, A. Chlorine; B. Chloric Acid; C, Acid based decomposition of chlorates, Optical Activity, Crystallography of the Chlorates, Molar and ionic magnetic susceptibility, Density of saturated solutions, Boiling point elevation by chlorates in solution, Free energy of formation, Entropy (S, cal/degree/mole), Entropy (Cp, cal/degree/mole), Heat of dilution (cal/mole); D; E. Toxicity of chlorates; Chlorate Hazards; F. Perchloric Acid; G. Properties of the perchlorates, Reactions, The general properties of the perchlorates, Melting points of perchlorates, Molar and ionic magnetic susceptibility, Density of saturated aqueous solutions, The index of refraction at temperature, Heat of formation, Free energy of formation, Entropy, Entropy, Heat of solution (Kg cal/mole), Heat of dilution (cal/mole), Solubilities of some alkali metal perchlorates in selective organic solvents, The Explosive properties of chlorates and perchlorates, Toxicity of the cations of chlorates and perchlorates, Amine Perchlorates, Physical properties of nitroguanidine perchlorate, Ignition temperatures of amine perchlorates, Impact sensitivities of methyamine perchlorates, Non-Metallic Perchlorates, Physical properties of boron perchlorates, Thermal decomposition of metal perchlorates other then alkali perchlorates, Addition of perchlorates to Propellants' to increase burn properties; Section 3: The analysis of chlorates and perchlorates, Qualitative analytical methods for chlorates, Quantitative analytical methods for chlorates, Qualitative analytical methods for perchlorates, Quantitative analytical methods for perchlorates; Section 4: Group 1a Chlorates, A. Lithium chlorate; B. Sodium chlorate; General Information; C. Potassium chlorate, General information, Catalytic Decomposition; Section 5: Group 2a Chlorates; A. Magnesium chlorate; B. Calcium chlorate; C. Barium chlorate; Section 6: Group 1a Perchlorates; A. Lithium Perchlorate, General properties; B. Sodium Perchlorate, General Information; C. Potassium Perchlorate, General information; Section 7: Group 2a Perchlorates; A. Magnesium perchlorate, General information; B. Calcium perchlorate, General information; C. Barium perchlorate General information; Section 8: Metal chlorates and Perchlorates; A. Aluminum chlorate, General Information; B. Aluminum perchlorate, General information; C. Silver chlorate General information; D. Nickel perchlorate, Reactions of nickel perchlorate with DMSO (dimethyl sulfoxide); E. Titanium perchlorate, Preparation (from titanium tetrachloride and chlorine perchlorate); F. Silver perchlorate, General information; Section 9: Ammonium Chlorate and Perchlorate; A. Ammonium Chlorate, Explosive properties of ammonium chlorate; B. Ammonium Perchlorate, General information; Section 10: Halogen Chlorates and Perchlorates, A. Perchloryl Fluoride (PF); B. Chlorine Perchlorate; C. Bromine Perchlorate; D. Iodine Perchlorate; Section 11: Nitrosyl and Nitronium Perchlorates; A. Nitrosyl Perchlorate; B. Nitronium Perchlorate (NP); Section 12: Miscellaneous Perchlorates, A. Hydrazine perchlorate; Hydrazinium monoperchlorate (HP); B. Hydrazine diperchlorate; Hydrazinium diperchlorate (HDP); C. Guanidinum perchlorate; D. Hydroxylamine perchlorate; Hydroxyl-ammonium perchlorate; E. Complex Perchlorates; Section 13: Chlorate and Perchlorate cells, A. Chlorate cells; B. Perchlorate cells; Section 14: References

• Format: Paperback
• Language: English
• ISBN: B086L16YFF
• ISBN13: 9798632226844
• Release Date: March 2020
• Publisher: Independently published
• Length: 506 Pages
• Dimensions: 11.0" x 1.3" x 8.5"