Phospa-S-Triazines and Related Compositions of Improved Hydrolytic and Thermal Stability

By National Aeronautics and Space Administration

The objective of the Program was to synthesize novel degradation inhibitors for perfluoropolyalkylether fluids and to evaluate their performance as well as that of other available inhibitors. Four novel additives: (C3F7OCF(CF3)CF2OC(CF3)2CN)((C6H5)2PN)2, (C3F7O(CF(CF3)CF2O)2C(CF3)2CN)((C6H5)2PN)2, u-(C3F7OCF(CF3)CF2OC(CF3)2CN)2((C6H5)2PN)2 and C3F7(OCF(CF3)CF2)6C6H4OP(O)(OC6H5)2 were prepared, characterized and their thermal stabilities established. The alloys studied were: 440C steel, M-50 steel, Pyrowear 675, Cronidur 30, Ti (4Al, 4Mn), and Ti (6Al, 4V). The additives and metals were evaluated in two different lots of Fomblin Z25, in Krytox 143AC and in Krytox 16256. Phosphate esters were found to be fully effective in arresting perfluoropolyaucylether fluid's degradation at temperatures up to 300 C over 24 h in the presence of alloys in oxygen. The overall rating of additives was: phosphates greater than phosphate/diester mixture greater than phosphine grater vthan or equal to phpospha-s-triazines. Paciorek, K. J. L. Glenn Research Center PERFLUORO COMPOUNDS; INHIBITORS; THERMAL STABILITY; SYNTHESIS (CHEMISTRY); PHOSPHATES; ESTERS; INFRARED SPECTRA; ADDITIVES; PHOSPHINES; ETHERS; DEGRADATION; ALLOYS; OXYGEN; NUCLEAR MAGNETIC RESONANCE; METAL SURFACES; TEMPERATURE EFFECTS; FLUIDS...

• Format: Paperback
• Language: English
• ISBN: 1731569726
• ISBN13: 9781731569721
• Release Date: January 1
• Publisher: Independently Published
• Length: 180 Pages
• Weight: 0.95 lbs.
• Dimensions: 0.4" x 8.5" x 11.0"