General Introduction.- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides.- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands.- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes.- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives.- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.
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