Preface.- Mechanistic insights into surface-supported chemical reactions.- Kinetic and thermodynamic considerations in on-surface synthesis.- Heat or light? Tools of choice for on-surface synthesis.- Reactivity on and of graphitic substrates at the liquid-solid interface: scanning probe microscopy reveals.- C-H activation as a generic route for on-surface synthesis of complex macromolecules.- Dehydrogenative and dehalogenative homocoupling reactions of C-X groups on metal surfaces.- On-surface Ullmann reaction for the synthesis of macrocycles and polymers.- Bottom-up fabrication of atomically precise graphene nanoribbons.- Aryl-aryl covalent coupling on rutile TiO2 surfaces.- On-surface synthesis of 2D networks: from graphene-like to graphyne-like networks.- Cu- and Pd-catalyzed on-surface coupling reactions.- nc-AFM to Address Long-Standing Chemical Challenges.
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