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Paperback Memory Functions, Projection Operators, and the Defect Technique: Some Tools of the Trade for the Condensed Matter Physicist Book

ISBN: 3030686663

ISBN13: 9783030686666

Memory Functions, Projection Operators, and the Defect Technique: Some Tools of the Trade for the Condensed Matter Physicist

Dedication page

Acknowledgments

Foreword

Authors' Preface

1 The Memory Function Formalism: What and Why

1.1 Introduction to Memory Functions

1.2 An Example of How Memory Functions Arise: the Railway-Track Model

1.3 An Overview of Areas in which the Memory Formalism Helps

2 Zwanzig's Projection Operators: How They Yield Memories

2.1 The Derivation of the Master Equation: a Central Problem in Quantum Statistical Mechanics

2.2 Memories from Projection Operators that Diagonalize the Density Matrix

2.3 Two Simple Examples of Projections and an Exercise

2.3.1 Evolution of a Simple Complex Quantity

2.3.2 Projection Operators for Quantum Control of Dynamic Localization

2.3.3 Exercise for the Reader: the Open Trimer

2.4 What is Missing from the Projection Derivation of the Master Equation

3 Building Coarse-Graining into the Projection Technique

3.1 The Need to Coarse-Grain

3.2 Constructing the Coarse-Graining Projection Operator

3.3 Generalization of the F orster-Dexter Theory of Excitation Transfer

3.4 Obtaining Realistic Memory Functions

3.5 Implementing a General Plan

3.5.1 Example in an Unrelated Area: Ferromagnetism

4 Features of Memory Functions and Relations to Other Entities

4.1 Resolution of the Perrin-F orster-Davydov Puzzle

4.2 Relations Among Theories of Excitation Transfer

4.3 Long-range Transfer Rates as a Consequence of Strong Intersite Coupling

4.4 Connection of Memories to Neutron Scattering and Velocity Auto-Correlation Functions, and Pausing Time Distributions

5 Applications to Experiments: Transient Gratings, Ronchi Rulings, and Depolarization

5.1 Non-drastic Experiments: Fluorescence Depolarization as an Example

5.2 Ronchi Rulings for Measuring Coherence of Triplet Excitons

5.3 Fayer's Transient Gratings: an Ideal Experiment for Measuring Coherence of Singlet Excitons

6 Projection Operators for Various Contexts

6.1 Projections for the Theory of Electrical Resistivity

6.2 Projections that Integrate in Classical Systems

6.2.1 The BBGKY Hierarchy

6.2.2 Torrey-Bloch Equation for NMR Microscopy

6.3 Projections for Quantum Control of Dynamic Localization

6.4 Projections for the Railway-Track Model of Chapter 2

7 Memories and Projections in Nonlinear Equations of Motion

7.1 Extended Nonlinear Systems and the Physical Pendulum

7.2 Nonlinear Waves in Reaction Di_usion systems

7.3 Spatial Memories: Inuence Functions in the Fisher Equation

8 NMR Microsocopy and Granular Compaction

8.1 Pulsed Gradient NMR Signals in Con_ned Geometries

8.2 Analytic Solutions of a Generalized Torrey-Bloch Equation

8.3 Non-local Analysis of Stress Distribution in Compacted Sand

8.4 Spatial Memories and Correlations in the Theory of Granular Materials

9 Projections/Memories for Microscopic Treatment of Vibrational Relaxation

9.1 The Importance of Vibrational Relaxation

9.2 The Montroll-Shuler Equation and its Generalization to the Coherent Domain

9.3 Reservoir E_ects in Vibrational Relaxation

9.4 Approach to Equilibrium of a Simpler System: a Non-Degenerate Dimer

10 The Montroll Defect Technique

10.1 Introduction: Experiments that Modify Substantially

10.2 Overview of the Defect Technique and Simple Cases

10.2.1 Trapping at a Single Site

10.2.2 How Laplace Inversion may be avoided in Some Situations

10.2.3 Trapping at More than 1 Site: Exercise for the Reader

10.3 Coherence E_ects on Sensitized Luminescence

10.4 End-Detectors in a Simpson Geometry

10.5 High Defect Concentration: the _-fun

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