Homo- and Heterobimetallic Complexes in Catalysis: Cooperative Catalysis

Book Overview

Bimetallic templates to perform catalysis: the case of ethylene polymerization and hydroamination.- Functionalization of alkynes mediated by bimetallic catalysts. Nucleophilic additions, cross-coupling reactions, addition reactions, pericyclic reactions.- Dinuclear rhodium complexes in the hydroformylation reaction of alkenes.- Early-Late bimetallic complexes in functionalization reactions. Cyclopropanation of styrene (Ta-Ru), Kumada coupling of unactivated alkyl chlorides with alkyl Grignard reagents (Zr-Co), Hydrosilylation of ketones (Zr-Co, Ti-Rh, Nb-Rh).- Transmission of the electronic information through the metal-metal bond in dinuclear templates. CH activation (RuI), epoxidation of alkenes (RhII).- Hydrogenation reactions catalyzed by di-rhodium and di-iridium complexes. Alkynes, alkenes, imines.- Biomimetic complexes for the production of dihydrogen, reduction of CO2.- Synergism introduced by a second metal in catalysis. Reactivation of the catalyst; Catalytic binuclear elimination reaction. Hydroformylation, carbonylation of methanol.

• Format: Paperback
• Language: English
• ISBN: 3319816950
• ISBN13: 9783319816951
• Release Date: June 2018
• Publisher: Springer
• Length: 277 Pages
• Weight: 0.91 lbs.
• Dimensions: 0.6" x 6.1" x 9.2"