The monograph is devoted to the electrodeposition of nanostructured multilayer zinc-nickel alloy coatings from pyrophosphate-citrate electrolytes. The formation of multilayer (Zn-Ni)base/(Zn-Ni)add]n coatings and stripping voltammetry for monitoring phase composition of the sublayers are discussed. The influence of periodic architecture on grain refinement and intermetallic distribution is substantiated. The advantages of multilayer structures in enhancing microhardness and corrosion protection of steel are demonstrated. The monograph will be useful for researchers, manufacturers of galvanic coatings, as well as academic staff and students in the fields of materials science and chemical technology.
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