Provided is a method for preparing a catalyst for a dehydrogenation reaction of formic acid, the method including: preparing a nitrogen-doped carbon support; forming a mixed solution including a first aqueous metal precursor solution which includes palladium (Pd) and a second aqueous metal precursor solution which includes nickel (Ni); and forming a catalyst for a dehydrogenation reaction of formic acid by stirring the nitrogen-doped carbon support with the mixed solution, and then immobilizing alloy particles of Pd and Ni on the nitrogen-doped carbon support.
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